I really like Syncthing, Nextcloud, Forgejo and Mailcow to collaborate with colleagues.
Kimai allows me to track hours and get paid.
Barrier allows me to use several computers at once.
Xen Orchestra is pretty much on par with VMWare stuff and way cheaper.
What other awesome software does allow you to work more efficiently in a business context and stays out of your way?
I think it depends on your business. I used Libreoffice, Python, ImageJ, R, VirtualBox, Ubuntu, and large Linux clusters for a couple of decades.